Daisuke Sakamoto
Research interest

Organic catalysis

Related Publication and Patents

4. One-Pot Synthesis of (R)-Baclofen via Aldol Condensation of Acetaldehyde with Diphenylprolinol Silyl Ether Mediated Asymmetric Michael Reaction as a Key Step
Yujiro Hayashi, Daisuke Sakamoto, and Daichi Okamura

3. Asymmetric Mannich reaction of alpha-keto imines catalyzed by diarylprolinol silyl ether.
Hayashi Y, Sakamoto D, Shomura H, Hashizume D.
Chem. Eur. J., 19, 7678 (2013).

2. One-Pot Synthesis of Chiral Aziridines by a Domino Reaction by Using Desulfonylative Formation on the N-Tosyl Imine of Chloroacetaldehyde with an Asymmetric Mannich Reaction as a Key step
Y. Hayashi, T. Urushima, D. Sakamoto, K. Torii and H. Ishikawa
Chem. Eur. J., 17, 11715 (2011).

1. Enantio- and Diastereoselective Synthesis of Piperidines by Coupling of Four Components in a "One-Pot" Sequence Involving Diphenylprolinol Silyl Ether Mediated Michael Reaction
T. Urushima, D. Sakamoto, H. Ishikawa, and Y. Hayashi
Org.Lett., 12, 4588 (2010).